Help me understand devotion chance to hit

Unlocked my first devotion ability (acid spray) and I’ve noticed it has two different chances to happen depending upon which skill I assign it to:

For a Curse of Frailty it has a 15% chance on attack.

For Dreeg’s Evil Eye it has a 63% chance on attack.

Why the difference?

Also does every tick of Dreeg’s evil eye’s poison have a chance to proc it or just the initial hit? If it hits multiple enemies (from Blood Burst explosion) do they all have individual rolls to proc Acid Spray?

It’s based on the cooldown of the assigned skill. I assume you have the Dreeg’s Evil Eye transmuter which gives the skill a cooldown. CoF has no CD at all.